Photoacoustic spectroscopy of formaldehydewith tunable laser radiation at the parts per billion level 287 FIGURE 2 Measured PA spectrum of 10 ppmv formaldehyde and ∼2.3% water. European J. Unimolecular decay of metastable ions in formaldehyde, ; Warneck, P., J. Chem.
The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Relat. , The electronic spectrum of formaldehyde. All rights reserved. Processes in Geophysics, Atmospheric
J. The reflectivity of the two cavity mirrors used herein was 0.99965 (1 – reflectivity = 350 ppm loss) at 350 nm, which corresponded with an effective optical path length of 2.15 km within a 0.84 m cavity.
The photoionization of vapors of compounds whose molecules contain carbonyl groups, Mass Spectrom., 2000, 6, 443. Figure S1, details of the Y-type fiber bundle; Figure S2, transmissions of three optical filters; Figure S3, HCHO concentrations retrieved from two fit ranges; Figure S4, convoluted absorption cross sections of typical UV gas absorbers; Figure S5, continuous measurement results of reference spectra with 30 s time resolution; Figure S6, regression plot of binned HCHO IBBCEAS measurements against the Hantzsch measurements (PDF).
The absorption spectrum of formaldehyde at 1.573μm has been recorded at room temperature with a typical sensitivity of 6×10-8cm-1 by using an off-axis integrated cavity output spectroscopy set-up based on a distributed feedback diode laser. Daniel Mariuta, Arumugam Govindaraji, Stéphane Colin, Christine Barrot, Stéphane Le Calvé, Jan G. Korvink, Lucien Baldas, Jürgen J. Brandner. The combined light source based on a Y-type fiber bundle overcomes the difficulty of measuring ambient HCHO via IBBCEAS in near-ultraviolet range, which may extend IBBCEAS technology to measure other atmospheric trace gases with high precision. [all data], Vilesov, 1960
Geology and Geophysics, Physical
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard More than 140 lines have been recorded within the laser spectral range (6351.3 – 6362.1 cm-1).The corresponding spectral … Your institution may already be a subscriber. Geophysics, Marine The infrared absorption spectrum of formaldehyde has been further investigated to beyond 11.0μ and bands were located at wave-lengths 5.7μ, 6.7μ, 7.5μ, 8.6μ and 9.6μ in addition to the regions originally reported by Salant and West and Patty and Nielsen near wave-lengths 3.5μ, 1.8μ, 1.4μ and 1.25μ. Heat of formation for the formyl cation by photoionization mass spectrometry, Find more information on the Altmetric Attention Score and how the score is calculated.
Indian J. Mass Spectrom. We expect six fundamental vibrations (12 minus 6), and these have been assigned to the spectrum absorptions.
Database and to verify that the data contained therein have and Paleomagnetism, History of ; Krauss, M.; Neumann, D.,
Ion Phys., 1975, 18, 65. Niu, B.; Shirley, D.A.
. Int. ; Turner, D.W., Physics, Comets and [all data], Karpas and Klein, 1975 Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. To see the formaldehyde molecule display a vibration, click one of the buttons under the spectrum, or click on one of the absorption peaks in the spectrum. Phys. [all data], Traeger, 1985
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi with the development of data collections included in Planets, Magnetospheric Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Guyon, P.M.; Chupka, W.A. The far ultraviolet absorption spectra of formaldehyde and the alkyl derivatives of H, O and H2S,
[all data], Brand and Reed, 1957 However, HCHO detection via traditional incoherent broadband cavity enhanced absorption spectroscopy (IBBCEAS) is limited by short optical path lengths and weak light intensity. Matthews, C.S. Dokl. and Informatics, Vibrational and/or electronic energy levels, Electron-Impact Ionization Cross Sections (on physics web site), Computational Chemistry Comparison and Benchmark Database, X-ray Photoelectron Spectroscopy Database, version 4.1, NIST / TRC Web Thermo Tables, "lite" edition (thermophysical and thermochemical data), NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data), Enthalpy of formation of positive ion at 0K, Free energy of reaction at standard conditions, Enthalpy of reaction at standard conditions. Chem.
; Moule, D.C., [all data], Matthews and Warneck, 1969
Kimura, K.; Katsumata, S.; Achiba, Y.; Yamazaki, T.; Iwata, S., J. Chem. Ref. Photoionisation von methanol und formaldehyd, Phys., 1986, 84, 2520.
on behalf of the United States of America. Ion Phys., 1968, 1, 285.
Price, W.C., Relat.
in Handbook of HeI Photoelectron Spectra of Fundamental Organic Compounds, Japan Scientific Soc. Phys., 1957, 26, 542. To see the formaldehyde molecule display a vibration, click one of the buttons under the spectrum, or click on one of the absorption peaks in the spectrum.
J. Phys. The higher Rydberg states of formaldehyde, This article is cited by The purpose of the fee is to recover costs associated and Petrology, Exploration Objects, Solid Surface Vilesov, F.I.,
, 1957, 2386.
Absorption Spectra For Key Species We have built a prototype formaldehyde instrument operating at 1.778 mm (5625.85 cm-1). © 2018 by the U.S. Secretary of Commerce Planetary and Space Science 1980 , 28 (7) , 675-679. Phys., 1976, 65, 1419. Get article recommendations from ACS based on references in your Mendeley library.
shall not be liable for any damage that may result from [all data], Guyon, Chupka, et al., 1976 15 formaldehyde absorption spectrum in the near UV between 300nm and 350nm (Fig.
[all data], Hernandez, Masclet, et al., 1977
Files available from the ACS website may be downloaded for personal use only. Collaborative Innovation Centre of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science & Technology, Nanjing 210044, China P. R. Sensitive Detection of Ambient Formaldehyde by Incoherent Broadband Cavity Enhanced Absorption Spectroscopy. Hernandez, R.; Masclet, P.; Mouvier, G., Int. 30.4 nm He(II) photoelectron spectra of organic molecules. Part III. The American Chemical Society holds a copyright ownership interest in any copyrightable Supporting
%PDF-1.3 %�������������������������������� 1 0 obj << /Type /ExtGState /OP true /op true >> endobj 2 0 obj << /Type /ExtGState /OP false /op false >> endobj 3 0 obj << /Type /ExtGState /OP true /op true >> endobj 4 0 obj << /Type /ExtGState /OP false /op false >> endobj 5 0 obj << /Type /ExtGState /OP true /op true >> endobj 6 0 obj << /Type /ExtGState /OP false /op false >> endobj 7 0 obj << /Type /ExtGState /OP true /op true >> endobj 8 0 obj << /Type /ExtGState /OP false /op false >> endobj 9 0 obj << /Type /ExtGState /OP true /op true >> endobj 10 0 obj << /Type /ExtGState /OP false /op false >> endobj 11 0 obj << /Type /ExtGState /OP true /op true >> endobj 12 0 obj << /Type /ExtGState /OP false /op false >> endobj 13 0 obj << /Type /ExtGState /OP true /op true >> endobj 14 0 obj << /Type /ExtGState /OP false /op false >> endobj 15 0 obj << /Type /ExtGState /OP true /op true >> endobj 16 0 obj << /Type /ExtGState /OP false /op false >> endobj 17 0 obj << /Type /ExtGState /OP true /op true >> endobj 18 0 obj << /Type /ExtGState /OP false /op false >> endobj 19 0 obj << /Type /ExtGState /OP true /op true >> endobj 20 0 obj << /Type /ExtGState /OP true /op true >> endobj 21 0 obj << /Type /ExtGState /OP false /op false >> endobj 22 0 obj << /Type /ExtGState /OP true /op true >> endobj 23 0 obj << /Type /ExtGState /OP false /op false >> endobj 24 0 obj << /Type /ExtGState /OP true /op true >> endobj 25 0 obj << /Type /ExtGState /OP false /op false >> endobj 26 0 obj << /Type /ExtGState /OP true /op true >> endobj 27 0 obj << /Type /ExtGState /OP false /op false >> endobj 28 0 obj << /Type /ExtGState /OP true /op true >> endobj 29 0 obj << /Type /ExtGState /OP false /op false >> endobj 30 0 obj << /Type /ExtGState /OP true /op true >> endobj 31 0 obj << /Type /ExtGState /OP false /op false >> endobj 32 0 obj << /Type /ExtGState /OP true /op true >> endobj 33 0 obj << /Type /ExtGState /OP false /op false >> endobj 34 0 obj << /Type /ExtGState /OP true /op true >> endobj 35 0 obj << /Type /ExtGState /OP false /op false >> endobj 36 0 obj << /Type /ExtGState /OP true /op true >> endobj 37 0 obj << /Type /ExtGState /OP false /op false >> endobj 38 0 obj << /Type /ExtGState /OP true /op true >> endobj 39 0 obj << /Type /ExtGState /OP true /op true >> endobj 40 0 obj << /Type /ExtGState /OP false /op false >> endobj 41 0 obj << /Type /ExtGState /OP true /op true >> endobj 42 0 obj << /Type /ExtGState /OP false /op false >> endobj 43 0 obj << /Type /ExtGState /OP true /op true >> endobj 44 0 obj << /Type /ExtGState /OP false /op false >> endobj 45 0 obj << /Type /ExtGState /OP true /op true >> endobj 46 0 obj << /Type /ExtGState /OP false /op false >> endobj 47 0 obj << /Type /ExtGState /OP true /op true >> endobj 48 0 obj << /Type /ExtGState /OP false /op false >> endobj 49 0 obj << /Type /ExtGState /OP true /op true >> endobj 50 0 obj << /Type /ExtGState /OP false /op false >> endobj 51 0 obj << /Type /ExtGState /OP true /op true >> endobj 52 0 obj << /Type /ExtGState /OP false /op false >> endobj 53 0 obj << /Type /ExtGState /OP true /op true >> endobj 54 0 obj << /Type /ExtGState /OP false /op false >> endobj 55 0 obj << /Type /ExtGState /OP true /op true >> endobj 56 0 obj << /Type /ExtGState /OP false /op false >> endobj 57 0 obj << /Type /ExtGState /OP true /op true >> endobj 58 0 obj << /Type /ExtGState /op false >> endobj 59 0 obj << /Type /ExtGState /OP true /op true >> endobj 60 0 obj << /Type /ExtGState /OP false /op false >> endobj 61 0 obj << /Type /ExtGState /OP true /op true >> endobj 62 0 obj << /Type /ExtGState /OP false /op false >> endobj 63 0 obj << /Type /ExtGState /OP true /op true >> endobj 64 0 obj << /Type /ExtGState /OP false /op false >> endobj 65 0 obj << /Type /ExtGState /OP true /op true >> endobj 66 0 obj << /Type /ExtGState /OP false /op false >> endobj 67 0 obj << /Type /ExtGState /OP true /op true >> endobj 68 0 obj << /Type /ExtGState /OP false /op false >> endobj 69 0 obj << /Filter /FlateDecode /Subtype /Type1C /Length 15926 >> stream