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F~Ӽ(L�|�` 2010 Mar;75(3):333-7. doi: 10.1111/j.1747-0285.2009.00933.x. https://doi.org/10.1007/BF00170916, Over 10 million scientific documents at your fingertips, Not logged in The deactivation occurred in the repetitive batch as well. You can change your cookie settings through your browser. In: Schneider MP (ed) Enzymes as catalysts in organic synthesis. The intracellular thermodynamic activity coefficients of acetophenone and phenethyl alcohol were predicted to be 471.2 and 866.4, respectively, using the measured initial distribution coefficients and calculated extracellular activity coefficients. (2004) Bioelectrochem On a cadmium cathode, the major product is the alcohol whereas on a zinc cathode, the pinacol is rather obtained. DeepDyve's default query mode: search by keyword or DOI. Part of Springer Nature. The addition of Mg 2+ ions was found to be necessary to prevent rapid deactivation. A 70-fold enrichment of the enzyme with an overall yield of 76% was obtained in two steps. %PDF-1.6
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Equilibrium conversions were observed in the range of 60.2-76.0% with different initial compositions of reaction media for the bioreduction of acetophenone using resting cells of Saccharomyces cerevisiae in aqueous solutions at 30 degrees C. The reduction of acetophenone in the cells under anaerobic conditions is considered to be coupled with the oxidation of ethanol to acetate in the cytoplasm. Tax calculation will be finalised during checkout. 2003 Mar;19(2):206-11. All the latest content is available, no embargo periods. To achieve 98% conversion of acetophenone, cofactor regeneration by oxidation of 2-propanol with the same enzyme was used. Reset filters. You can see your Bookmarks on your DeepDyve Library. 2004 Oct 1;111(2):115-22. doi: 10.1016/j.bpc.2004.05.003. Handle9041649, PubMed 2005 Jan 1;433(1):335-40. doi: 10.1016/j.abb.2004.09.033. Tetrahedron 42:3351–3403, Keinan E, Seth KK, Lamed R (1987) Synthetic applications of alcohol-dehydrogenase from Thermoanaerobium brockii. PubMed Google Scholar. To subscribe to email alerts, please log in first, or sign up for a DeepDyve account if you don’t already have one. Recl. IssueID1 Unlimited access to over18 million full-text articles. 1994 Nov 20;44(10):1217-27. doi: 10.1002/bit.260441009. It’s your single place to instantly HBCM Google Scholar, M (2003a) Wandrey The column tem- tration of (R)-1-phenylethanol and (S)-1-phenyl ethanol perature was held at 110 C: (R)-o-chlorophenethylic (mol/L) respectively. Kragl Chem. National Center for Biotechnology Information, Unable to load your collection due to an error, Unable to load your delegates due to an error. Greiner 25 | Handle3683199, M-R The addition of Mg2+ ions was found to be necessary to prevent rapid deactivation. Zhao Y(1), DeLancey GB. h�b```f``Jf`e`�� Ā B,@Q�WZʎ��9����
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Anal Biochem 72:248–254, Article U Correspondence to - 95.110.169.160. Trav. h��O�8��G%~?�-ۃ]^K{�T*-j�w�3v��IJs=�����o��2� %L �)��$�3x+"���&NxCb+X�u `�*�k��s��@��^�A�UN��P�/�p#�pg��%�3���[J�rЫa(@É0�"W H"��"�1�0�%�on�4 Asymmetric reduction of acetophenone by various plants tissue (Yand et al., 2008) Asymmetric reduction of ketones catalyzed by plants tissue (Yang et al., 2010) Scheme.1. Biotechnol Bioeng. Kruse Find any of these words, separated by spaces, Exclude each of these words, separated by spaces, Search for these terms only in the title of an article, Most effective as: LastName, First Name or Lastname, FN, Search for articles published in journals where these words are in the journal name, /lp/springer-journals/the-asymmetric-reduction-of-acetophenone-and-its-derivatives-to-s-VL2FHH6oYv, Industrial biocatalysis today and tomorrow, Schmid, A; Dordick, JS; Hauer, B; Kiener, A; Wubbolts, M; Witholt, B, Recent advances in the biocatalytic reduction of ketones and oxidation of sec-alcohols, Kroutil, W; Mang, H; Edegger, K; Faber, K, Interaction of beta-cyclodextrin as catalyst with acetophenone in asymmetric reaction: a theoretical survey, ProPhenol-catalyzed asymmetric additions by spontaneously assembled dinuclear main group metal complexes, Asymmetric transfer hydrogenation of prochiral ketones in aqueous media with chiral water-soluble and heterogenized bifunctional catalysts of the RhCp*-type ligand, Barron-Jaime, A; Narvaez-Garayzar, OF; Gonzalez, J; Ibarra-Galvan, V; Aguirre, G; Parra-Hake, M; Chavez, D; Somanathan, R, Asymmetric reduction of ketones and beta-keto esters by (S)-1-phenylethanol dehydrogenase from denitrifying bacterium Aromatoleum aromaticum, Dudzik, A; Snoch, W; Borowiecki, P; Opalinska-Piskorz, J; Witko, M; Heider, J; Szaleniec, M, Efficicent (R)-phenylethanol production with enantioselectivity-alerted (S)-carbonyl reductase II and NADPH regeneration, Zhang, R; Zhang, B; Xu, Y; Li, Y; Li, M; Liang, H; Xiao, R, Biochemical and structural characterization of recombinant short-chain NAD(H)-dependent dehydrogenase/reductase from Sulfolobus acidocaldarius highly enantioselective on diaryl diketone benzil, Pennacchio, A; Sannino, V; Sorrentino, G; Rossi, M; Raia, CA; Esposito, L, Investigation of asymmetric alcohol dehydrogenase (ADH) reduction of acetophenone derivatives: effect of charge density, Naik, HG; Yeniad, B; Koning, CE; Heise, A, Enantioselective reduction of acetophenone and its derivatives with a new yeast isolate Candida tropicalis PBR-2 MTCC 5158, Biocatalytic anti-Prelog reduction of prochiral ketones with whole cells of Acetobacter pasteurianus GIM1.158, Metabolomics for biotransformations: intracellular redox cofactor analysis and enzyme kinetics offer insight into whole cell processes, Schroer, K; Zelic, B; Oldiges, M; Lutz, S, Towards the discovery of alcohol dehydrogenases: NAD(P)H fluorescence-based screening and characterization of the newly isolated Rhodococcus erythropolis WZ010 in the preparation of chiral aryl secondary alcohols, Yang, C; Ying, X; Yu, M; Zhang, Y; Xiong, B; Song, Q; Wang, Z, Dynamics of the cellular metabolome during human cytomegalovirus infection, Munger, J; Bajad, SU; Coller, HA; Shenk, T; Rabinowitz, JD, Resting cells of recombinant E. coli show high epoxidation yields on energy source and high sensitivity to product inhibition, Julsing, MK; Kuhn, D; Schmid, A; Buhler, B, Highly enantiomeric reduction of acetophenone and its derivatives by locally isolated Rhodotorula glutinis, Asymmetric reduction of substituted acetophenones using once immobilized Rhodotorula glutinis cells, Kurbanoglu, EB; Zilbeyaz, K; Ozdal, M; Taskin, M; Kurbanoglu, NI, Efficient biocatalytic synthesis of (R)-[3,5-bis(trifluoromethyl)phenyl] ethanol by a newly isolated Trichoderma asperellum ZJPH0810 using dual cosubstrate: ethanol and glycerol, Li, J; Wang, P; He, JY; Huang, J; Tang, J, Asymmetric reduction of ethyl pyruvate to (S)-ethyl lactate by yeast resting cells, Wang, D; Zhang, Q; Li, W; Qi, NC; Guo, CX; Yang, ZR; Zhang, J, Enzyme identification and development of a whole-cell biotransformation for asymmetric reduction of o-chloroacetophenone, Kratzer, R; Pukl, M; Egger, S; Vogl, M; Brecker, L; Nidetzky, B, Enzymatic Production of Bioxylitol from Sawdust Hydrolysate: screening of Process Parameters, A novel carbonyl reductase with anti-Prelog stereospecificity from Acetobacter sp. Clipboard, Search History, and several other advanced features are temporarily unavailable.