202-867-2 Molecular Formula C₆H₅MgBr Product Number 408465 APPLICATION Grignard-reactions: reagent for the introduction of the phenyl group.
Articles of phenylmagnesium bromide … 100-58-3 EC-No. Extremely flammable liquid and vapor. }e����e��7���^��U�~���E�����8�����_!u|=({�ʢ����� !�{�(}N�u����5 ����t������c�&@�+�E��w0R{(��(0ǚ`h��e��g+��I�[�������h6�k�x�?S�ď�Cc�������+��국h�k\x�>���ɚ��S����Bj��mAu��M���t. MDL number MFCD00000038. Material is extremely destructive to the tissue of the mucous membranes and upper respiratory tract. Phenylmagnesium bromide, 1.6M solution in CPME Revision Date 10-Apr-2018 required.
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1. 61 0 obj <>/Filter/FlateDecode/ID[<96853E914305DB16370BCB20E6D1A1C8><1931119E7E326045926AA60E9492B170>]/Index[37 39]/Info 36 0 R/Length 109/Prev 95884/Root 38 0 R/Size 76/Type/XRef/W[1 2 1]>>stream NACRES NA.22 Company Identification: Acros Organics N.V. One Reagent Lane Fair Lawn, NJ 07410 For information in North … Molecular Weight 306.31 . It can abstract even mildly acidic protons, thus the substrate must be protected where necessary. PubChem Substance ID 24855569 Hazard Statements. 3.4-methylene dioxy-phenyl-magnesium bromide. Details of the supplier of the safety data sheet Emergency Telephone Number During normal business hours (Monday-Friday, 8am-7pm EST), call (800) 343-0660. Label elements Signal Word Danger Hazard Statements H225 - Highly flammable liquid and vapor H302 - Harmful if swallowed H314 - Causes severe skin burns and eye damage H412 - Harmful to aquatic life with long lasting effects EUH019 - May form explosive peroxides f`e`�� �� @V�2?����"k̼�7T0T@ĀB��i�@Z���:��f�]�z�Rఠ���'��7�^�]��v�����S?O�à �Nh�! hޜV�n�8��yl���E")�ǮS�uDަ���f���M�~gHɱӸIm��p��%p��P�A����?���#����A舃 b�� ��9��2�����lT�U�lӕ�I�)�$#
37 0 obj <> endobj 3,4-(Methylenedioxy)phenylmagnesium bromide 0.5 M in Tetrahydrofuran. 0 Molecular Weight 181.31 . 75 0 obj <>stream 2.8 M) CAS-No. Chemsrc provides phenylmagnesium bromide(CAS#:100-58-3) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200) Label Elements. ���!��IE�=i(�7���Ub��O��>�lZ�;��}�r�î���@�bZHP�#P�#CPQG*PqGj{.V��ȃ��MG����kP��DN�����"��d���k���Eb�%�n�̀��%�?n�SyX���� m��ʖ-�\�Q��h��}�s���qW�$O7 ���zX�k,�y q�Q�L��I'i���u��g�s�����&mm��=���c���!���i����&��Y���+ġ_�RZu�m��}�K�-��F:]��Zg��f�l��|��M;�O�~EON ��%��NC͒�w-ş�?�Kd� �^���B�I�D� �� � .iM_ Linear Formula C 6 H 5 MgBr . Hazard(s) identification. Signal Word. %PDF-1.5 %���� Hazards not otherwise classified No information known. H314 (98.59%): Causes severe skin burns and eye damage [ Danger Skin corrosion/irritation] Information may vary between notifications depending on impurities, additives, and other factors. Skin Harmful if absorbed through skin. MDL number MFCD07369723. Vapours may cause drowsiness and dizziness. Phenylmagnesium bromide is a strong nucleophile as well as a strong base. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. 200-467-2 Benzene CAS-No. endstream endobj startxref Classification. With carbon dioxide, it reacts to give benzoic acid after an acidic workup. 71-43-2 EC-No. 3,4-(Methylenedioxy)phenylmagnesium bromide, 0.50 M in 2-MeTHF. Ingestion may cause damage to the mouth, throat and esophagus. Aspiration hazard no data available Potential health effects Inhalation May be harmful if inhaled. If three equivalents are reacted with phosphorus trichloride, triphenylphosphine can be made.
200-753-7 SPECIFICATION Phenylmagnesium Bromide: … Additional toxicological information: Swallowing will lead to a strong corrosive effect on mouth and throat and to the danger of perforation of esophagus and stomach.
q��=�(t�G �4��n�9-c"7�6�< Fu���y�HB���=�!y��9�hgOR�(��Ъ����>��=>�? Phenylmagnesium bromide, 1.6M solution in CPME Revision Date 08-Mar-2019 2.2. endstream endobj 38 0 obj <> endobj 39 0 obj <> endobj 40 0 obj <>stream Visit ChemicalBook To find more PHENYLMAGNESIUM BROMIDE(100-58-3) information like chemical properties,Structure,melting point,boiling point,density,molecular formula,molecular weight, physical properties,toxicity information,customs codes. Empirical Formula (Hill Notation) C 7 H 4 BrF 6 Mg . h�b```f`` %%EOF Application Phenylmagnesium bromide (PhMgBr) solution is an organomagnesium reagent mainly used in Grignard reaction, which finds application as the key step in the synthesis of (S)-2(diphenylmethyl)pyrrol idine, a chiral solvating agent for the NMR analysis.PhMgBr can also undergo palladium-catalyzed Grignard coupling with alkyl chlorides to form the cross-coupled product in good … ��`�>J�&U�"o>�� 3,5-Bis(trifluoromethyl) phenylmagnesium bromide solution 0.5 M in THF CAS Number 112981-69-8. Immediate medical attention is required. 60-29-7 EC-No.
It can react with chromium trichloride in diethyl ether solution to generate dibenzenechromium.
Remove and wash contaminated clothing and gloves, including the inside, before re-use. Label elements GHS label elements The product is classified and labeled in accordance with 29 CFR 1910 (OSHA HCS) Hazard pictograms GHS02 GHS05 Signal word Danger Hazard-determining components of labeling: Phenylmagnesium bromide P260 No smoking. Phenylmagnesium Bromide, typ. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. You can also browse global suppliers,vendor,prices,Price,manufacturers of PHENYLMAGNESIUM BROMIDE(100-58-3).