MECHANISM FOR REACTION OF ALKENES WITH Br2 / H2O.

Anti addition to give the cis product. Anti addition to give the trans product. Ch 6: Alkene + X2 / H2O. Bromonydrin formation is addition reaction of Br and OH across the alkene and the product is called a bromohydrin (bromo=bromine, hydrin=hydro, water/H 2 O).

Syn addition to give the trans product. Chemistry Q&A Library When Br2 and H20 react with an alkene to generate a bromohydrin, which stereochemical course does the mechanism take? The π electrons act as a nucleophile, attacking the bromine, displacing a bromide ion but forming a cationic cyclic bromonium ion as an intermediate. This reaction is the reaction between alkenes and halogens. When you have light plus Br2 plus an alkene you get allylic bromination, which means a bromine radical removes a hydrogen (and one electron from its bond) from a carbon adjacent to the double bond (in allylic position), leaving only one electron on that carbon which reacts with another Br2 to take one of the bromines and one of its electrons to form a halogenated alkene and another bromine radical in the … Reaction of alkene and liquid bromine If one double exists in the alkene molecule, it reacts with one molecule of Br 2 and two bromine atoms are added to the alkene to form alkyl halide compounds. Syn addition to give the cis product.

Step 1: Same first step as for the reaction of Br 2 /CH 2 Cl 2 . This reaction proves, alkenes are unsaturated organic compounds. Step 2: Attack of the nucleophilic water molecule from the side away from the bromonium center opens the … Bromohydrin Formation Explained: Lewis acid like the bromine is able to bond to the alkene π electrons, and the resulting complex rearranges or is attacked by nucleophiles to give addition products.